Thermal degradation of hemicellulose and cellulose in ball-milled cedar and beech wood

نویسندگان

چکیده

Abstract The thermal degradation reactivities of hemicellulose and cellulose in wood cell walls are significantly different from the behavior respective isolated components. Furthermore, Japanese cedar ( Cryptomeria japonica , a softwood) is distinct that beech Fagus crenata hardwood). Lignin uronic acid believed to play crucial roles governing this behavior. In study, effects ball milling for various durations time on woods were evaluated based recovery rates hydrolyzable sugars pyrolyzed samples. applied ball-milling treatment cleaved lignin ?-ether bonds reduced crystallinity cellulose, as determined by X-ray diffraction. Both xylan glucomannan degraded similar temperature range, although components exhibited because catalytic effect bound xylose chains. These observations can be explained more homogeneous distribution matrix result milling. As observed holocelluloses, ball-milled two ranges (below 320 °C above); significant amount lower which changed shapes thermogravimetric curves. This report compares results obtained woods, discusses them terms microfibrils role lignin. Such information understanding pyrolysis heat wood.

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ژورنال

عنوان ژورنال: Journal of Wood Science

سال: 2021

ISSN: ['1435-0211', '1611-4663']

DOI: https://doi.org/10.1186/s10086-021-01962-y